Melissa ramirez

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Owing to tremendous technological advances, computational chemistry has evolved into a powerful tool for the development of reactions used to construct complex molecules. Computational models that allow chemists to predict the selectivity of a reaction are highly sought after because they enable rapid and efficient construction of intricate scaffolds. The first part of the presentation will detail computational studies onthe reaction of strained alkynes and arynes with oxadiazinones and the application of this reaction to the synthesis of non-symmetric polycyclic aromatic hydrocarbons. Several mechanistic aspects of the transformation were interrogated using density functional theory DFT calculations, including the differing reactivities of non-aromatic strained alkynes versus arynes. Experimental studies also demonstrated the rapid synthesis of polycyclic aromatic hydrocarbons, including tetracene and pentacene scaffolds, using this synthetic platform. The second part of the presentation will center on the development of an asymmetric Ni-catalyzed intramolecular cyclization of lactones to generate spirocyclic scaffolds using a combination of experiments and computations. This work is anticipated to expand the application of Ni-catalyzed nitrile insertion for quaternary center generation and to enable the exploration of new chemical space in drug discovery.

Melissa ramirez

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Ramirez, 29, was one of four people police say were shot and killed by U. All died of gunshot wounds to the head, their bodies dumped in rural stretches of nearby Laredo. I should have gone looking for her. Authorities named Ramirez, Claudine Ann Luera, 42, and Humberto Ortiz, 28, as the victims and were still trying to identify a fourth victim. Police said Juan David Ortiz, a year veteran of U.

Melissa ramirez

Get the best experience and stay connected to your community with our Spectrum News app. Learn More. Juan David Ortiz , 39, receives an automatic sentence of life in prison without the possibility of parole because prosecutors decided not to seek the death penalty. Their bodies were found along roads on the outskirts of Laredo in September Following the verdict, family members of the victims faced Ortiz to give their statements. Ramirez's sister-in-law, Gracie Perez, said she was "a loving, kind and funny person. Defense attorneys said Ortiz was improperly induced to make the confession and that it should not be considered. Defense attorney Joel Perez argued that Ortiz, a Navy veteran who had been deployed to Iraq, was suffering from post-traumatic stress disorder, had been suffering from insomnia, nightmares and headaches, and was medicated and had been drinking that night. Prosecutors told jurors it was a legal confession provided by an educated senior law enforcement official who was not having a mental breakdown.

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Makeup Department as Melissa Jimenez, Colombia. Stargirl 7. More to explore. Credits Edit. Westworld 8. Titans 7. Breadcrumb home Dr. Experimental studies also demonstrated the rapid synthesis of polycyclic aromatic hydrocarbons, including tetracene and pentacene scaffolds, using this synthetic platform. Personal details Edit. The Walking Dead 8.

In September , a border town in Texas was rattled after four women who were sex workers were found dead.

They Live in the Grey 5. Suicide Squad. Makeup Department as Melissa Jimenez, seaming. Learn more about contributing. Stargirl 7. Credits Edit. The 9th Life of Louis Drax 6. Contribute to this page Suggest an edit or add missing content. The Boys 8. Alita: Battle Angel. Mile Additional Crew 1 Thanks 1. The Walking Dead 8. The Hateful Eight 7.